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What type of Epoxy?

5K views 24 replies 16 participants last post by  WoodenDreams 
#1 · (Edited by Moderator)
I'm a little lost.
I've heard a lot about West Systems epoxy, a fair amount about System Three, and I've personally used a ton of the big box store brands like Locktite, Permatex, and Harbor Freight stuff.

I don't really trust the 5-minute-cure Locktite or Harborfreight stuff though for some of the things I want to do. On the other hand, I don't need a huge gallon or even quart can of the West Systems stuff.

I want to use for things like gluing up oily exotic woods, and making those large, important joints like trestle table legs. I want plenty of open time (1/2 hour or so)

Got any recommendations? Specific?
 
#3 ·
I use West systems with the 206 slow hardener. It has it place but it also has some drawbacks. In some woods it will leave a dark glue line, it's very expensive so mixing up the right amount without being wasteful is challenging.
Mostly I use tite bond or plain old Elmer's glue. I try to carefully plan my glue up in the cool mornings evenings.
 
#4 · (Edited by Moderator)
West Systems, and System 3 are the same company now.

For Joinery stuff - I use "T-88" from System 3.
Available a lot of places, I get it on Amazon.

Gel time is 60 minutes, full cure is 72 hours, but generally I find it is an "overnight" clamp-up and is no longer tacky… just takes 72 hours to be at full strength.

Comes in many sizes from 1/2 pints to gallons.
https://www.systemthree.com/products/t-88-structural-epoxy-adhesive

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#5 ·
there are dozens of good epoxy products on the market.
you just have to weed through them to fine one that works for you.
I keep a supply of the West System G/flex 650 on hand. it is a slow set
and easy to work with - and cheaper than the quart kits.

Liquid Product Bottle Fluid Personal care


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#7 · (Edited by Moderator)
All clear retail (IE sold in retail store) epoxies are basically same stuff. :(

Best example - Bob Smith Industries provides private labeling programs for any hobby shop or distributor that buys in bulk. That is why Hobby Lobby/Rockler/Woodcraft epoxy or cyanoacrylate adhesives all come in same bottle(s) and look almost same - they are same!


The key difference between the hardware store 5/10/15/60 minute cure varieties sold in less than 1 quart bottles is the type of curative used. They all use similar blends of same resins (bisphenol A diglycidyl ether & bisphenol F diglycidyl ether, with maybe some low viscosity reactive diluent oligomers).

The FAST cure (less than 15 min) types use an aromatic amine curative that reacts quickly and is least temperature sensitive of typically retail epoxy curatives. These are most forgiving of stupid human tricks, like mix ratio errors, or cooler temps. :)

The SLOW cure (30 minute plus) types use an polyimide curative that reacts much slower, and cure speed is much more dependent on ambient temp. Some will NOT cure at all below 60F, or will take weeks to cure, and months to reach full strength. These are less forgiving of stupid human tricks; such as mix ratio errors, and dirty bond surfaces, etc.

Generally speaking, The shorter the cure time; the lower bond strength, and lower bond strength is at elevated temperatures. So despite challenges with longer cure time epoxies, one should always use the longest cure time your process allows for best adhesive performance. Also must know that while fast/slow epoxy may begin cross linking and 'set' in 5 or 30 minutes, that full bond strength is not reached for days, some even require weeks (length of time is temperature dependent).

The small bottle retail epoxies described above are different than epoxy systems typically sold by West Systems, System 3, etc; in quarts and gallons. These epoxies were developed for (fiberglass, Kevlar, carbon fiber) composite lamination of water and air craft parts. These laminating resins have significantly lower viscosity to help with fabric wet out. They use slightly different resin and curative blends to provide this lower viscosity. These lower viscosity resins typically have lower bond strength (PSI), but when used over large area strength is not as important as flexibility or consistent performance across a wide range of temperatures.

The strength of laminating resin .vs a structural resin is mute point for most wood working applications. We really only need to be concerned with shear strength and peel strength. Practically every retail branded structural or laminating epoxy is stronger than wood in these stress modes. :)

So you can choose an epoxy to use for wood working based on how much time you need for assembly, clamp retention time, ambient temperature during assembly & cure, and even price. :)

Hope this helps explain hobby epoxy for you.

PS -
There are also retail structural epoxies intended for metal bonding, these are typically grey or black in color. This 'metal' epoxies use powdered metal as fillers, and weak acids that react with epoxy system to etch the metal for stronger bond. JB Weld is common brand, and it uses flake aluminum powder to help dissipate heat in epoxy and improve high temperature performance. Devcon/Loctite sell a black epoxy that uses powdered steel as filler for bonding metal castings. These can be used for bonding wood, but would not be best choice.

NOTE:
The above is extreme simplification of differences between varies retail epoxy types. There many more subtle differences left out, and many more epoxy systems available from commercial/online sources that some might consider retail materials. If you need more information on epoxy adhesives, PM me offline, and I can suggest a couple of polymer reference books for your library. :)

Best Luck!
 
#8 ·
Capt. Klutz! Wow, thanks! Very interesting. I learned a lot.
The strength of laminating resin .vs a structural resin is mute point for most wood working applications. We really only need to be concerned with shear strength and peel strength. Practically every retail branded structural or laminating epoxy is stronger than wood in these stress modes. :)

So you can choose an epoxy to use for wood working based on how much time you need for assembly, clamp retention time, ambient temperature during assembly & cure, and even price. :)

- CaptainKlutz
This does not surprise me, makes sense. ^
 
#13 ·
I've used the West System G/flex 650 extensively; and, aside from the epoxy-associated issues, it is excellent.

Epoxies tend to leave a thicker, more noticeable glue-line (though TB3 is noticeable on light woods); and is much more expensive. The longer open time is very helpful in specific situations; and, in exterior work (outdoor benches, for example), I would default to epoxy.

These days, all interior builds are TB3 (Titebond III).

MCJD
 
#14 ·
Couple more data points for those that care about epoxy differences:

1- The epoxy systems designed for composites mentioned above can have significant differences in material properties depending on curative used, even with same resin. While most people only look at whether curative is fast, med, or slow; these same curatives can provide significantly different values for hardness, flexibility, water resistance, or clarity (yellowing). So while picking your curative for optimum cure time, be sure to check the overall properties are what you need.

2- There are many epoxy suppliers available online. Not saying anything bad about West Systems, or System 3 'retail' brands; but if your application needs quarts/gallons of epoxy, WWW has cheaper sources. I have used Fibreglast for many, many years with great success. Us Composites private label epoxies also offer nice price break with as few as 2 gallons. :)

3- If you are interested in longevity of epoxy in any surface coating applications where you want minimal yellowing as it ages, do not forget to protect the epoxy with UV inhibiting top coat. ALL epoxies will turn yellow as they age and are exposed to UV, even the 'clear' top coat epoxies sold for coating bar tops.

Best Luck!
 
#15 ·
Is it a "mute" point or is it a "moot" point?

- ArtMann
Technically, it should be a 'mute' point, as 'moot' means something that is arguable. This is why law students participate in a 'moot court'. However, as with so many misspoken phrases, the term 'moot point' is considered something not worth arguing.

It's like when you hear someone say 'pompom' when the term is actually 'pompon'. A 'pom-pom' is actually a British naval gun.
 
#17 · (Edited by Moderator)
I'm with the Capin.

I started buying larger quantities because of the infinite uses to which I can put it.

The last go round was two to one mix and I enjoy the long open time, and the fact it flows enough I can even use it to harden wood. Waiting twenty-four hours is just to be expected to me, since, if you're going be using epoxy, you probably already expected to have to wait a while.

I think you'd be hard pressed to be able to show it was significantly weaker than 3-M or other brands.
 
#18 ·
I have seen marine epoxies at the big box stores. Does this mean some epoxies are affected by moisture or water?
I had always thought epoxies were waterproof.
- Pixxture
Water Proof or Moisture resistant? Epoxy? Adhesive or Coating? Which chemistry is being used?

Short answer:
Yes, 'epoxy' can be affected by moisture!

Long answer:
Depends…..

First: Key part of the 'water proof' performance of any polymer depends on conditions for: temperature, pressure, and PH. Using epoxy at room temp with atmospheric pressure can make it look waterproof. But same epoxy subjected to high pressure steam, or an acidic liquid, and it will fail in minutes/hours

While epoxy is considered to be more resistant to water permeation/absorption than other polymer materials, epoxies are not 100% 'waterproof'. Some are just more resistant to water than others. :) Aliphatic epoxy systems are generally more water resistant than aromatic epoxy systems, and usual what is sold as 'marine epoxy'.

Hmm, Could spend pages explaining this topic.

Good example reference: Sherwin Williams offers every practical epoxy chemistry used in epoxy coating market. This PDF comparison of chemistry types shows differences in final properties.
These same curative chemistries are used by epoxy adhesives (although maybe not available at retail), but I am unable to find an online comparison documentation ATM.

BTW -
If you really, really, really want to see the kind of engineering work that goes into finding the perfect epoxy for use with wood, try reading this NC State University paper on epoxy selection for engineered wood (glue lam beams).
My favorite part of paper is 1st conclusion:
None of the epoxy variations tested had any impact on overall strength performance.
Hahahaha - Just as I posted earlier, most all epoxies will work for wood bonding. :)

My apologies for diving into a rabbit hole on this topic; I have spent over half of my 35 year professional career, developing materials, and processes involving epoxy, polyurethane, & silicone polymer systems for electronics industries. Bonding wood is easy by comparison…....

Cheers!
 
#22 ·
The small bottle retail epoxies described above are different than epoxy systems typically sold by West Systems, System 3, etc; in quarts and gallons. These epoxies were developed for (fiberglass, Kevlar, carbon fiber) composite lamination of water and air craft parts. These laminating resins have significantly lower viscosity to help with fabric wet out. They use slightly different resin and curative blends to provide this lower viscosity. These lower viscosity resins typically have lower bond strength (PSI), but when used over large area strength is not as important as flexibility or consistent performance across a wide range of temperatures.

- CaptainKlutz
Lots of good information here but I have to disagree with the characterization of WEST and System Three epoxies as low viscosity laminating resins. I was never a WEST fan and won't speak for them although I'm pretty sure my point applies to them as well.
When I was building boats I used many many gallons of "marine epoxy" from a company called Industrial Formulators of Canada which has since been bought out by System Three. IFC offered a wide range of epoxies for all kinds of purposes, some with special bonding additives for oily woods, some food grade, some for cloth lamination, etc, etc.
Some were very high viscosity and some were very low.
Most of these products are still sold by System Three, many under the same names (ColdCure, S1 sealer, etc.)
My advice to anyone who is looking at using epoxy for a specific purpose is to talk to an epoxy supplier who knows his product and take their advice.
I was lucky enough to have known Jim Peters who was the chemist who founded IFC and was able to get my advice directly from him. There is a lot of complexity in the subject of epoxies.
 
#23 · (Edited by Moderator)
..
My advice to anyone who is looking at using epoxy for a specific purpose is to talk to an epoxy supplier who knows his product and take their advice.
..
There is a lot of complexity in the subject of epoxies.
- shipwright
Ahmen!
Have worked with every major raw material supplier and formulator in world on epoxy resins, curatives, and modifiers; for several decades in automotive, aerospace, and electronics products. Even if you are a part time formulator like me with a half dozen adhesive patents and own a cabinet full of raw materials to make your own formulas, it it best to work with your local supplier for a solution. :)

It IS extremely hard to generalize any mfg. All I was comparing was classic small bottle 5-15-40 minute cure retail grades to the common named epoxies sold for boat or aerospace lamination sold in retail stores. It was not meant as all encompassing. Most mfg make structural and laminating systems, plus hundreds of specialty systems designed for special bonding cases. Picking right one can be very hard.

There are volumes of books on the topic and college degrees available if you want to learn more.

#IAMAKLUTZ, not any sort of an expert.

Cheers!
 
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